Nice introductory article from the author of Knoppix Hacks.
http://www.onlamp.com/pub/wlg/5964Knoppix is pretty easy to remaster and many people have created their own Knoppix variant to suit their needs. However there are a number of tweaks and changes you can make that don't require a complete remastering if you take advantage of the knoppix.sh script. I'll go over some of the advantages to this approach over a full remastering below.
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