The menu entry "KNOPPIX > Services > Start NX Server" runs the shell script /usr/bin/nxsetup-knoppix as root. There are a couple of errors creating the "nxuser" user, and the script fails. To avoid the errors, before running the script:
1. Start the "portmap" daemon ("/etc/init.d/portmap start")
2. Remove the symlink /etc/gshadow ("rm /etc/gshadow") and copy a writeable "gshadow" to /etc ("cp /KNOPPIX/etc/gshadow /etc").
Now run the script.
(If you set a password for the regular knoppix user, you can log into the NX client on your other computer as "knoppix").

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